Spray Instant Pot™ insert with cooking spray. Mix broth, rice, salt and pepper in insert.
Stir in chicken and broccoli. Secure lid; set pressure valve to SEALING. Select MANUAL or PRESSURE COOK ; cook on high pressure 10 minutes. Select CANCEL. Set pressure valve to VENTING to quick-release pressure.
Stir in cheese. Broccoli will break down when stirring.
Notes
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For a pretty pop of green on top, sprinkle with chopped fresh parsley leaves.
For best browning, pat chicken pieces dry before tossing with salt and poultry seasoning.